����JFIF�����%%��� }!1AQa"q2���#B��R��$3br� %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz������������������������������������������������������������������������� w!1AQaq"2�B���� #3R�br� $4�%�&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz��������������������������������������������������������������������������?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|��O�������h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@��o�E��/�?��ߵE_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ ?�z�����������goڢ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?��=[�Qg�����o����Q@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y�����[����TP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,���|-��v��(���� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�������;~��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@�������?�_�����j������ (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@��o�E��/�?��ߵE_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ ?�z�����������goڢ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?��=[�Qg�����o����Q@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y�����[����TP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,���|-��v��(���� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�������;~��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@�������?�_�����j������ (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@��o�E��/�?��ߵE_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ ?�z�����������goڢ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?��=[�Qg�����o����Q@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y�����[����TP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,��������ο�O�P��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@����(���g���Y������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���V��Y|����Y����UP��@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P����,�����,��u������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j���h�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� �@���o�E��?�?����ο�U_�P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@ _�z�����������g_ڪ�?��(�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (��?�/�=[�Qe�����g����U@��P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������k�w���~���v��������� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (�� (���տ�_�����:��T�~�@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@P@������/���?��j�?�5o�%��?��� g����U@�����&O3�����a�;�^=�wH���D��/��*� �fX�I���,������k?g_���?�5o�%��?��� g����U@�F�����������*������?�o�}��Τ~g��ʀ�#V��Y������~ο�T�j��K/� ������������z��������#;�~���A�;��� w�F�����������*���տ��_�@�o��5����EU������������u�誠��W��[�����������O��?jW���@��տ���@�o��5����EM������������v�訠�#V��Y�������������V��Zv��~����vw�~���c�Q@���,��~���kgo���?�5o�%��/��� o����Q@��o�%�>�ߤ���߳����S������?��o�%�~�ߠ�d�߳����S����g�P��j��K?� _������������[� g�D����[�;�TP7���������'Ѿ���=��;/�P��j��K?� _������������[� g�D����[�;�TP���,��~���kgo���a������۔���B{���ea�`T�+ �n%Ц �����j��K?� _������������[� g�D����[�;�TP���,��~���kgo����?���%�/�~�����#����x��c�~�q�v�t`ȫ��_'h���������'�]�;{s� Pp=N= 5���%�����ڜs�����=���J��A@�����Kp�b��}��X�����4g v+:�Բ�+60�ʩ,� @�����������I �uO�����ToUv��bgUl�cP�T?�#V��Y������������j��K?� _����������!��X��]���������TK�|4��`� ��#��P\y��aa >NgL��j��K?� _������������[� g�D����[�;�TP���,��~���kgo���o�F�����$��ہ�� ��vݞr6��S�q''*02���[� g�D����[�;�TP���,��~���kgo���?�5o�%��/��� o����Q@�F�����������*(��տ���@�o��5����EE������������v�訠��������~1�o���}G�L�������5o�%��/��� o����Q@�F�����������*(��տ���@�o��5����EE5����%�˷���r�v����y�\~���)(?0���=[� i����>��gc��N=����5o�%��/��� o����Q@�F�����������*(��W��Z�l����m#���X�wn_�j`0C6윅����5o�%��/��� o����Q@��տ��y9���gbO�G�5@�n�>���#V��Y������~ο�T��V��Y����9�gc��s�T.�?Z_��[� e�D����Y�:��UP���,������k?g_����_�=_� n�~~�rI������w�,"~ԓ�!72���)( u��#V��Y������~ο�T�j��K/� ��������������K
�����Kr_���}�De>~��Z=��pjX�n[p(�"� �a,Ub�/�×�<����;��<�����K>��o���[�:����V���,��$��ϧ�*�����5O����տ��_�@�o��5����EU5��o�%����?�ꜜm�_�;>Gbs�S�����@��տ��_�@�o��5����EU ��տ��}�~�����v?�������-��o�l��~�ȥ�v����r��B1���@��տ���A�?����ggP��c�S�`@%�*����տ��_�@�o��5����EU������������u�誠7���� O���!c�|0��ёv��4�+�X�Vx�RX3��8����K>��o���[�:���u#�x��#V��Y������~ο�T�j��K/� ������������[� e�D����Y�:��UP���,������k?g_���O��[� g�D����[�:��T��=_� k����~��k����c�;����.8����c��z��Ͽ�/��zc�o����F?Z_��[� e�D����Y�:��UP���,������k?g_���C���,�v����v�o���H������(�z���w�/�����v ��T.G��Ϡ���տ��_�@�o��5����EU������������u�誠��W��[��'����%��o���:�Cڕ�R̀���j���������?�o���[�;������g0q�?��o�%�>o�_��>�gf����~4�������������u�誠�z���7�/��o���������_��[� e�D����Y�:��UP���,������k?g_���C���,�|�����o��;�Ԟ��9�l�z��ؠ3|��O�X�~���;~�q����Z�F�����������*���տ��_�@�o��5����EU!��տ��}�~����-��G��I�T�������������u�誠�#V��Y������~ο�T�j��K/� ����������#�=_� n|���KbB�gtdM��"�ڒA#n�63�6�m�P�����,���/���gS�u����#�9��5o�%��?��� g����U@��o�%�o�_�����u��'�������?��o��� ���3��?go���|m�ڇ���-S�O��x��>���^�����7����x�]_�>�qke>���m��4��7P�Yހ��
0byt3m1n1
0byt3m1n1
Path:
/
hermes
/
bosweb
/
web
/
b2920
/
robertgrove.netfirms.com
/
nsoc0k
/
cache
/
[
Home
]
File: f464289d8b87ecd4dee28295d58e73ec
a:5:{s:8:"template";s:1357:"<!DOCTYPE html> <html lang="en"> <head> <meta charset="utf-8"> <meta content="width=device-width, initial-scale=1.0, maximum-scale=1.0, user-scalable=no" name="viewport"> <title>{{ keyword }}</title> <style rel="stylesheet" type="text/css">body,div,html{margin:0;padding:0;border:0;font-size:100%;vertical-align:baseline}html{font-size:100%;overflow-y:scroll;-webkit-text-size-adjust:100%;-ms-text-size-adjust:100%}*,:after,:before{-webkit-box-sizing:border-box;-moz-box-sizing:border-box;box-sizing:border-box}body{font-family:Karla,Arial,sans-serif;font-size:100%;line-height:1.6;background-repeat:no-repeat;background-attachment:fixed;background-position:center center;-webkit-background-size:cover;-moz-background-size:cover;background-size:cover}</style> </head> <body class="lightbox nav-dropdown-has-arrow"> <div id="wrapper"> <header class="header has-sticky sticky-jump" id="header"> <div class="header-wrapper"> <div class="header-bg-container fill"> <h2>{{ keyword }}</h2> </div> </div> </header> <main class="" id="main"> {{ text }} </main> <footer class="footer-wrapper" id="footer"> {{ links }} <div class="absolute-footer dark medium-text-center text-center"> <div class="container clearfix"> <div class="footer-primary pull-left"> <div class="copyright-footer"> {{ keyword }} 2022</div> </div> </div> </div> </footer> </div> </body> </html>";s:4:"text";s:20202:"Materials to avoid Strong oxidizing agents, acids and alcohols. The drying agents commonly used in the organic laboratories are the anhydrous forms of calcium chloride (CaCl 2), sodium sulfate (Na 2 SO 4) Calcium sulfate (CaSO 4 (as Drierite) and magnesium sulfate (MgSO 4). . Two crosslinking agents have been used for the production of composites, i.e. Expert Answer. and compare amount of water in drying agent to amount in step 1 and step 3. Thirdly, it is best to use acidic agents for drying acidic materials, alkaline agents for alkaline materials, and neutral agents for neutral materials. Will not Precipitate 1: weigh drying agent. \(^4\)A. Seidell, Solubilities of Inorganic and Organic Substances, D. Van Nostrand Company, 1907. Example: 1 kg drying agent of capacity 20% can adsorb 200 g of water. class 12. Purpose : Calcium chloride in a drying tube is used in the form of pellets as a drying agent to remove the mositure from the air th . The safest method is to dry in a vacuum desiccator over concentrated sulphuric acid, phosphorus pentoxide, silica gel, calcium chloride, or some other desiccant. Those are for example: drying of liquids and neutral gases. All these pieces of glassware will need to be assembled after being in I think the procedure that Dr. John P. R. proposed is the most appropriate: Stirr dichloromethane with calcium chloride . If a second layer (water) is seen in the flask, remove it by pipette before addition of the drying agent. Keep in a dry place (such as a desiccator or a dry box or glove box). drying agent 824 results chem. This water must be removed before the required compound can be properly characterized. >> Anhydrous CaCl2 is used as drying agent, Question . Organic liquids are considered to be wet if they contain water,but the organic liquid will still be a liquid after it is dried. The hydrogen gas is allowed to escape from the system through a drying tube. wt's that? Under the reaction condition, hydrogen bromide is generated in the reaction mixture from its . Given its ionic nature it is easy for the substance . Or if any of the following reactant substances Cl2 (chlorine), disappearing. Each drying agent will have a . 2. What is the purpose of the CaCl2 drying tube? Firstly, make sure that the substance to be dried does not react with the agents. Most cacl2 drying agent add softness and bulkiness while increasing the tensile strength of the yarns. Reacts violently with water Explain. Many products are also . Used in . I just need the mechanism step by step. Another drying agent anhydrous CaCl2 was added to the solution This was done to. Click hereto get an answer to your question Conc. If I'm happy with it, I'm done, if I'm not return to step 2. It is hygroscopic, strongly attracting moisture from its surroundings. 1 . In some references regarding drying agents CaCl2 is mentioned as unsuitable for drying ketones. It is deliquescent. The efficiency of a drying agent (measured by intensity, capacity and velocity) can greatly vary from one solvent to the other. Ask Doubt. Queries asked on Sunday & after 7pm from Monday to Saturday will be answered after 12pm the next working day. separatory funnel. Calcium Chloride Anhydrous calcium chloride is a very hygroscopic compound, meaning that it readily absorbs water. Anhydrous CaCl2 cannot be used for drying alcohol, because (A) anhydrous CaCl2 is not a dehydrating agent (B) anhydrous CaCl2 does not exhibit delique . But I would. Chemical stability Stable under recommended storage conditions. The reaction occurs in the following way: CaCl2 + H2 + 2Na CaH2 + 2NaCl. The Gibbs free energy for the following reaction Na 2 SO 4 + 10 H 2 O ---- > Na 2 SO 4 * 10 H 2 O can be described by G = H - TDS = -77.8 kJ/mol - T (-261 J/mol*K) Based on this equation, it can be estimated that the reaction reverses at 298 K or 25 o C (G =0). That is it absorbs moisture from its surroundings hence it can be used as a dessicant. If the solution is dry then there still should be . 1. Calcium chloride in its anhydrous form is an economical drying agent and very important for drying processes in laboratories. CaCl2 is a more effective drying agent because it is anhydrous, meaning that the compound is deprived of water. H2SO4 , anhydrous CaCl2 or P4O10 cannot be used as drying agent for ammonia, why? . CaCl2 is a hygroscopic substance. Answer Question #1 on pg 173: which would be a more effective drying agent, CaCl2 or or CaCl26H2O. That means that it will keep absorbing water until, and even after it becomes a solution. The plant has been designed as a continuous process to produce dry HCL gas by the process of distillation of 30% hydrochloric acid solution along with a co-current stream of calcium chloride solution. Calcium chloride (CaCl2) is a compound that is highly soluble in water. The value of these properties is very apparent in key applications. Anhydrous calcium chloride works as a drying agent, and can be used particularly in shipping container desiccant poles, to protect cargo from condensation and label peel during transit. DRIERITE catalog and current prices. Stock up and ensure each garment is comfortable for customers and will last a long time, even with frequent wear. 3. It can even dissolve, in fact, in the water it absorbs from . Pages 6 Ratings 100% (4) 4 out of 4 people found this document helpful; The Chair Of Happiness, Anything But Christmas, Arsenic And Old Lace Play Characters, Belfast Strangler Netflix, A Walk Through The Year, See Me, Feel Me, Hear Me, Love Me, Touch Me, Share. Atoms Chemical Kinetics Moving Charges and Magnetism Microbes in Human Welfare Semiconductor Electronics: Materials, . Why is anhydrous CaCl2 is added to the flask which contains the ether solution. When dissolved in water, solid calcium chloride releases heat in an exothermic reaction. Remove the solvent using a rotary evaporator. Top 10 chemical reactions (balanced equation) that has CaCl2 as product substance, ranked by search volume. Contains calcium chloride, which has a high affinity for water and draws moisture out of the reaction vessel. Where substances are stable in air and melt above 100C, drying in an air oven may be adequate. Secondly, drying speed, drying effect and water absorption of the agents must be taken into consideration. Answered by | 25th Jun, 2013, 01:09: AM. The optimum technical conditions which use CaCl 2 and MgSO 4 compound reagent to treat coal-washing wastewater are determined by the orthogonal experiment. Anhydrous C a C l 2 is used as drying agent, because it. Kumar s answered on November 21, 2021. . Calcium chloride, CaCl 2 ( n =6, e=1.5 mg/L) is a good drying agent for a variety of solvents but is generally not compatible with molecules containing hydroxyl (alcohol, phenol), amino (amine, amide) and carbonyl (acid, ketone, ester) functional groups due to basic impurities such as Ca (OH) 2 and CaCl (OH). What chemical reaction is it preventing (pleasesupply a mechanism). The experimental results in laboratory are proved to be feasible through . Solid calcium chloride is deliquescent, meaning it can absorb enough moisture to convert to liquid brine. 4: use it to dry the acetone. Drying agents are used to remove trace amounts of water from an organic solution. Those are for example: drying of liquids and neutral gases. It is also a very good drying agent for a wide varie. In this case, you just need to observe to see if product substance CaCl2 (calcium chloride), appearing at the end of the reaction. 2CaOCl 2 O 2 + 2CaCl 2 BaCl 2 + Ca (OH) 2 Ba (OH) 2 + CaCl 2 CaO . Because of its mildness it is safer to use compared with more . Use drying agent (quick link to video : drying agents) In order to use a drying agent such as sodium sulfate or magnesium sulfate, the drying agent is just added to the solution using a spatula then the solution is stirred or swirled or shaken and set aside to settle for a couple of minutes. wt's that? ? 1. Here the calcium (Ca) and hydrogen (H) create a calcium hydride molecule while the sodium atoms join with chlorine, creating sodium choride molecules (NaCl). Calcium chloride as a drying agent for solutions. ? Drying tube. Solvents Drying and Drying Agents. A typical desiccant drying application involves a bed of anhydrous calcium chloride tablets, contained in a vertical vessel, through which the hydrocarbon is pumped. Always use an Erlenmeyer flask, not a beaker. . Assuming the following reaction proceeds in the forward direction, 3 Sn4+(aq) + 2 Cr(s) ---> 3 Sn2+(aq) + 2 Cr3+(aq) a.Sn4+(aq) is . increases the reaction surface, hence column length and packing material can be decreased. Calcium Chloride is an ionic compound with the chemical formula CaCl2. A. Adsorbs water molecule. 2. Lab Report. The drying agents commonly used in the organic laboratories are calcium chloride (CaCl2), sodium sulfate (Na2SO4) Calcium sulfate (CaSO4, as Drierite (R)) and magnesium sulfate (MgSO4), all in their anhydrous form. Potassium hydride is a mild drying agent. ca+cl2=cacl2 type of reaction. De lloyd's La b T e c h re sourc e s re a ge nt s a nd Solut ions Solve nt s Drying a nd Drying Age nt s Properties of solvents and methods used for drying them with specific drying agents Em a il Related link : Drying w it h sodium w ire : Disposal of spent sodium, magnesium and calcium hydride Re m oving w a t e r from Solve nt s There are various ways of . 1. For example if there is an Ethanol, water mixture which you want to dehydrate could you add Calcium chloride so . Anhydrous calcium chloride (CaCl2) pellets (instead of older granular form because the pellets do not disintegrate to give a fine powder) were preferred and used in this lab. The drying process was followed by scintillation readings, and several shortcomings were noted in "standard" drying prac-tices. While CaCl 2 is also a very common compound in laboratories and is employed as a drying agent for liquid or gas materials in desiccators or drying tubes, use of CaCl 2 as a reagent, in particular as a catalyst in organic synthesis, is very rare [8-10] (Recently, we reported chiral calcium chloride catalyzed 1,4-addition reactions, see , For . A drying tube prevents moisture from contaminating the reactants. Concentrated Sulphuric Acid is used as a drying and Dehydrating agent because it has a strong affinity for water and thus it absorbs water quickly. carried out using an apparatus called. Without the desiccating action of CaCl2, moisture will enter the reaction chamber,contaminating the reactants. Physicochemical properties (drying kinetics, swelling) and . This is the best answer based on feedback and ratings. . The Process. 3. That is it absorbs moisture from its surroundings hence it can be used as a dessicant. Was this answer helpful? It is anhydrous and therefore, its density is around 2.15. 2H2(g)+ O2(g) --> 2H2O(L) I know the oxidizing agent is oxygen and the reducing agent is hydrogen. With all drying agents, rinse the drying agent (in the flask and in the filter funnel) with a few \(\text{mL}\) of fresh organic solvent, and add the rinsing to the round-bottomed flask (Figure 4.53d). Phenomenon after Ca (calcium) reacts with Cl2 (chlorine) This equation does not have any specific information about phenomenon. 2. Capsules with various chemical composition were produced: pure alginate (ALG) and alginate with carboxymethylcellulose and different content of biosorbent (5 wt% and 10 wt%). I think the procedure that Dr. John P. R. proposed is the most appropriate: Stirr dichloromethane with calcium chloride . 0. Cu 2+ ions and Ca 2+ ions. 5: Remove drying agent. Anhydrous Calcium Chloride as a Drying Agent - FAQs. The drying process itself is slightly exothermic (H for the process is negative) but the entropy decreases during the drying . Heat the reaction flask to 60C using a heating mantle and reflux at 60C for 2 h. Under these conditions, calcium hydride reacts with water to form calcium hydroxide and hydrogen gas. What is the purpose of the CaCl2 drying tube? Drying agent was used because it removes water from the organic layer. Nov 19 2021 03:33 PM. Dry HCL Gas Generator Plant Manufacturer, Supplier and Exporter. supply a mechanism). Table 7.18: Procedural summary for using drying agents. It is used to prevent the ice formation and therefore used in deicing. Calcium chloride pellets in a drying tube act as desiccants or drying agents, removing moisture from the air that flows through them. * The capacity of our drying agent is defi ned by the mass of water adsorbed per 100 g anhydrous substance. Calcium oxide is used as drying agent for ammonia as both are basic in nature and do not undergo any reaction, while any acidic drying agent undergoes reaction with ammonia. 1. . However, this method typically reduces fl ow rates, . Process. . CaCl2 is a hygroscopic substance. The apparent answer is yes, to quote from a source (composed from extracts of old chemistry journal):. is widely used as a drying agent. The use of a drying tube is needed when the exclusion of moisture is required, but reaction under atmospherically inert conditions is not necessary. . Dry by keeping over anhydrous calcium chloride over night and then distill. In the simplest described definition, a drying agent, as it pertains to industrial and chemical processes, is a term given to a chemical that works to remove water from a compound that is currently in solution. The molecular mass or weight of the chemical is 110.98g. Also, many reactions themselves are performed in an aqueous solution. Answer: The Cost-Effective Choice for Your Drying Process Calcium chloride in its anhydrous form is an economical drying agent and very important for drying processes in laboratories. Possibility of hazardous reactions Reacts violently with water. It is also a very good drying agent for a wide variety of solvents. Despite this rather extensive analysis, many of the methods identified as inept are still in use today. In other cases, use of an Abderhalden pistol may be satisfactory. Have people successfully dried ketones with CaCl2? Listed below are the drying agents that are commonly used.Organic liquids are considered to be wet if they contain water. Abstract: Abstract-A new reagent is compounded by CaCl 2 and MgSO 4.It is determined through experiments that the proper mass ratio of CaCl 2 and MgSO 4 is 1:1. All the equation has been balanced, please click on each to view further details. in which the efficacy of several drying agents was investi-gated making use of tritiated water-doped solvents. Given its ionic nature it is easy for the substance . Peladow DG, a calcium chloride gas drying agent, is widely used as a desiccant for drying gases and liquid hydrocarbons within many industries due to its high affinity and capacity for absorbing water.. class 12. Below are all the equations which are searched the most from users of our system. Conditions to avoid Exposure to moisture. Organic layer is dry when a new small quantity of drying agent no longer clumps together, but the . What chemical reaction is it preventing (please supply a mechanism). . what are the number of electrons transferred in the balanced chemical equation? On evaporating a solution in ethyl alcohol at a low temperature rectangular plates of $\ce{2CaCl2.7C2H5OH}$ are deposited. Home > Uncategorized > ca+cl2=cacl2 type of reaction. School University of the Philippines Los Baos; Course Title CHEMISTRY 43; Type. Uploaded By jajafelice. Quote from: johnson039 on 04/03/2010 08:07:45. anhydrous calcium chloride is a common drying agent due to its hygroscopic nature, but my in my textbook said CaCl2 cannot dry ammonia gas becoz of formation of additional product. Oscillations Redox Reactions Limits and Derivatives Motion in a Plane Mechanical Properties of Fluids. Use drying agent (quick link to video : drying agents) In order to use a drying agent such as sodium sulfate or magnesium sulfate, the drying agent is just added to the solution using a spatula then the solution is stirred or swirled or shaken and set aside to settle for a couple of minutes. I'm aware of the reaction Calcium chloride has with water vapour and how it can therefore be used as a good and inexpensive drying agent but could that be applicable for solutions? What is the purpose of the CaCl2 drying tube? Is there a reason why? by March 24, 2021. reaction of calcium hydroxide with ammonium chloride in Solvay soda ash production and reaction of hydrochloric acid with . C. . Quote from: johnson039 on 04/03/2010 08:07:45. anhydrous calcium chloride is a common drying agent due to its hygroscopic nature, but my in my textbook said CaCl2 cannot dry ammonia gas becoz of formation of additional product. The reaction is the following: Ca(OH)2 + 2HCl = CaCl2 + 2H2O Will CaOH2 precipitate from solution if the pH of a .050 M solution of CaCl2 is adjusted to 8.0? . which one of the following anhydrous salts will be used as the drying agent for today's experiment? What is anhydrous calcium chloride? A compound that has been absorbing water for too long, or for an extended period of time, can become contaminated. Most cacl2 drying agent are easily soluble in water, making diluting them for safe use a simple task. Calcium chloride purum, drying agent, dehydrated, granulated, 97.0% (KT); CAS Number: 10043-52-4; EC Number: 233-140-8; Linear Formula: CaCl2; find Sigma-Aldrich-21074 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich 3: weight it again. University of Pretoria. Dry by keeping over anhydrous calcium chloride over night and then distill. . DRIERITE desiccants are Made In USA from the naturally occurring mineral, gypsum (Calcium Sulfate), and are available in several varieties designed to solve all types of drying problems. After 2 h, cool the reaction flask to room temperature (20-25C). CaCl26H2O is already hydrated and therefore not nearly as effective. Calcium chloride (n=6) is a very good drying agent for a broad variety of solvents but is generally not compatible with hydroxy (alcohol, phenol), amino (amine, amide) and carbonyl (acid, ketone, ester) functions due to basic impurities such as Ca(OH) 2 and CaCl(OH). Another drying agent anhydrous cacl2 was added to the. 0. 2: dry it in the oven. Oscillations Redox Reactions Limits and Derivatives Motion in a Plane Mechanical Properties of Fluids. Uncategorized 0 . Answer (1 of 2): The other answers state that calcium chloride is hygroscopic, but it is more than that. The compounds $\ce{CaCl2.3C2H5OH}$ and $\ce{CaCl2.CH3OH}$ have also been separated, as well as a mono- and a . Calcium chloride is suitable for drying acetone, ethers, numerous esters, aliphatic . DRIERITE is an all-purpose drying agent for the efficient and rapid drying of air, industrial gases, refrigerants, organic liquids and solids. Calcium chloride purum, drying agent, dehydrated, granulated, 97.0% (KT); CAS Number: 10043-52-4; EC Number: 233-140-8; Linear Formula: CaCl2; find Sigma-Aldrich-21074 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich 1 Approved Answer. Boiling and Melting Points of Calcium Chloride. The drying tube contains CaCl2 a hygroscopic material whose function is to absorb the moisture so that it does not react with the Grignard reagent. Start by adding a small portion of drying agent (size of . 5. University of Pretoria. If the solution is dry then there still should be . Calcium Chloride (CaCl 2 ) Uses. Calcium chloride forms addition compounds with the alcohols. The boiling point of calcium chloride is 1,935-degree centigrade and the melting point of the calcium chloride is 772-degree centigrade. >> Anhydrous CaCl2 is used as drying agent, Question . In the Organic Chemistry Teaching labs at CU, two methods of drying solutions are commonly used: saturated aqueous sodium chloride and solid drying agents. 1. B. Absorbs water molecule. 6: Weigh drying agent again. What chemical reaction is it preventing (please. ";s:7:"keyword";s:27:"cacl2 drying agent reaction";s:5:"links";s:1256:"<a href="https://www.mobileairstreamrepair.com/nsoc0k/knowledge-is-more-than-equivalent-to-force-origin">Knowledge Is More Than Equivalent To Force Origin</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/mint-foam-jordan-6-resell">Mint Foam Jordan 6 Resell</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/supercar-blondie-lexus">Supercar Blondie Lexus</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/how-to-break-gold-blocks-in-minecraft">How To Break Gold Blocks In Minecraft</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/gene-position-on-chromosome">Gene Position On Chromosome</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/2019-us-open-qualifying-results">2019 Us Open Qualifying Results</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/honda-civic-tenth-generation">Honda Civic Tenth Generation</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/subaru-cherry-blossom-festival-2022">Subaru Cherry Blossom Festival 2022</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/hori-switch-controller-not-connecting">Hori Switch Controller Not Connecting</a>, <a href="https://www.mobileairstreamrepair.com/nsoc0k/desert-eagle-1911-commander">Desert Eagle 1911 Commander</a>, ";s:7:"expired";i:-1;}
© 2017 -
ZeroByte.ID
.